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Chitin is the second
most abundant natural biopolymer in the world, behind only cellulose. It is
also the most abundant naturally occurring polysaccharide that contains
amino sugars. This abundance, combined with the specific chemistry of
chitin and its derivative chitosan, make for the array of potential
applications.
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Chitin occurs as a
component of crustacean shells, insect exoskeletons, fungal cell walls,
microtauna, and plankton, it is found in association with proteins and
minerals such as calcium carbonate. The different sources of chitin differ
somewhat in their structure and percentage of chitin content.
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Chemically, chitin is
a polymer formed primarily of repeating units of beta(1-4)
2-acetamido-2-deoxy-D-glucose (or N-acetylglucosamine). Its structure
resembles that of cellulose, except that the hydroxyl groups in position 2
have been replaced by acetylamino groups. Not every unit of naturally
occurring chitin is acetylated; about 16% are deacetylated
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Most commercial
applications use the deacetylated derivative, chitosan, rather than chitin.
Chitosan is a polysaccharide formed primarily of repeating units of beta
(1-4) 2-amino-2-deoxy-D- glucose (or D- glucosamine). Generally, about 80%
of the units are. deacetylated, with the remaining 20% acetylated. These
values can vary with chitin sources and with processing methods.
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Both chitin and
chitosan are traditionally known to be highly insoluble in water. This
characteristic has been a challenge for producers as well as end users of
these polymers. Everyone would like an easily water-soluble chitin and
chitosan
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With existing chitin
and chitosan extraction technology, physical characteristics were
considered attractive attributes, such as high molecular weight and small,
fine particle size. These physical attributes were needed to help overcome
the resistance of chitin and chitosan to solublize in water.
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MARINE CHEMICALS, Inc.
has produced a significantly more water-soluble chitosan. Our product, even
in large flake form, is fully and quickly soluble in a 1% acetic acid
solution. The purity of our product means that it is far more reactive then
conventional chitin or chitosan found on the market today.
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